.Solar PV technology is advancing very fast.
The solar power system that was once considered unattractive investment, is both technically viable and financially feasible.
We see many new technologies are evolving such as half-cut solar cell technology, Bi-facial solar panels, PERC solar modules, and many more.
The basic technology is still the same, it is either P-type or N-type.
Earlier, the application of the solar cells were limited to space satellites, the P-type solar cells are more immune to the space radiations. Hence we see more of them until 1980.
With continued research on N-type solar cells, their benefits are highlighted and we see highly efficient n-type solar modules in the market.
The latest solar technologies are the derivatives of these 2 types.
In this post, I will discuss the basics of P-type and N-type solar cells.
Speed of Light
The sun radiates electromagnetic energy, and it reaches the surface of the earth in around 8.33 minutes, covering almost 150 million kilometres with a speed of 3,00,000 km/sec.
The silicon solar cells absorb this electromagnetic energy and convert it into electrical energy.
Most of the solar energy is present in the visible spectrum of the light.
The solar spectrum looks like as shown below:
When you look closer you will find the dark lines in the spectrum, just like as shown below:
These dark lines are formed by the atoms in the earth’s atmosphere by absorbing energy corresponding to the precise wavelength of light.
These patterns of lines are unique and are called solar absorption spectra.
The electronic structure of an atom depends on how it absorbs and releases specific amount of energy.
The spectral lines are an effective tool to learn the electronic structure of an atom.
To jump to a particular orbit a specific amount of energy is required.
Therefore we can say that a photon’s energy should match with the energy required by the electron to jump to the specific orbit.
As the earth revolves around the sun due to the gravitational force; an electron revolves around the heavy nucleus (filled with positive protons and neutrons) in the center and its attractive electric force holds the electron in the orbit.
The electrons require energy to jump from the lower orbit to the higher orbit.
The electrons absorb the photons of light and jump to higher energy levels or orbits.
Similarly, when the electron falls back to the lower energy level, it must release the same amount of energy.
See how the photons of light with different energy can excite the electron to jump to the higher energy levels.
Each color is associated with different energy levels.
The Atomic Structure of Silicon
Silicon is a semi-conductor, it means that it shares some properties of metal and some of the insulator.
The four electrons in the outer most shell of the silicon are called valence electrons.
They can interact with the electrons of the other atoms to make chemical bonds.
The atomic structure of silicon is shown above, which is having atomic number 14. The electrons are shown in blue colors are revolving around the nucleus (red).
(The first orbit can hold up to 2 electrons, second and third orbits/shells can accommodate up to 8 electrons).
The first two orbits have 2 and 8 electrons respectively are filled and neutralized while the third orbit has 4 electrons in its valence shell.
The electrons in the valence shell tend to neutralize themselves and they find ways to do the same.
They try to go into a stable state through bonding called the covalent bond.
Now, when the photons of light fall on the surface of the silicon, the valence electrons absorb the photons and jump into a higher-energy conduction band.
In conduction band, the electrons are free to move and it is an unstable state.
Now, as electrons leave the valence band it creates the hole or it makes that region positive.
Those electrons which are promoted to the conduction band have a tendency to fall back to the valence band by releasing the absorbed energy and recombine with the hole to neutralize.
If we want to run our electrical appliances then we must pass these electrons through the electrical circuit before their recombination with the holes.
we can say that we need some force or electric field which can pull electrons present in the conduction band to pass through our electrical appliances.
Doping of Silicon
Now the question is how to create this force or electric field?
The answer to this question is the Doping of silicon with another impurity with similar electronic structure.
"Doping is a process where replacing a small number of silicon atoms with other atoms like Boron or phosphorous."
When we bring atoms (Silicon with Boron or Phosphorous) close to each other, the valence electrons of each atom will be attracted by the positive nucleus of the other atom.
In this way, the pair of electrons is shared forming the covalent bond structure.
One is called P-type which is made by adding impurities like Boron and the other is called N-type, which is formed by adding impurities like Phosphorous.
The P-type solar cell
The outermost shell of Boron has 3 electrons, which is one less than Silicon.
When Boron is added as an impurity with Silicon, then it forms 3 complete covalent bonds with the surrounding silicon atoms and leaves one incomplete bond.
Now, this incomplete bond pulls one electron from the valence electrons of other surrounding silicon atom.
This process leaves the hole or net positive charge in the silicon atom hence makes it a P type semiconductor.
N-type solar cell
The atomic number of Phosphorous is 15 and the outermost shell of Phosphorous has 5 electrons in its valence shell, which is one more than the Silicon.
When we add Phosphorous as an impurity in the silicon, it forms four complete covalent bonds with the neighboring silicon atoms.
The extra electrons are left in the valence band of the Phosphorous orbits around it. Now, as Phosphorous donates one extra electron to the silicon crystal hence it is called an N-type semiconductor.
When the P-type semiconductor and N-type semiconductor are attached then a junction is formed which is called PN junction.
Here electrons and holes are diffused across the PN junction and recombine.
The overall result of this process is the formation of net negative charge on the P side and net positive charge on the n side, forming an electric field across the junction.
When the photon of light falls on the PN junction, the electrons in the valence band will get excited and promoted to conduction band, leaving holes behind.
Before the recombination of the electrons with the holes, they are pulled apart and get separated by the electric field created by the PN junction.
The electrons with a negative charge move towards the positive field whereas the holes with the positive charge are attracted by the negative field.
This electric field has prevented the recombination of the electrons with a hole in the valence band.
This results in the generation of electric current which can pass through our appliances and run them.
On the silicon solar panel, the surface of silicon is covered and doped with a thin wafer of Boron to make it a P type semiconductor.
After that the atoms of Phosphorous are diffused on the surface creating a PN junction.
An anti-reflective layer is spread to prevent the reflection losses and increase the amount of absorption.
When you connect the electrical load across the panel under sunlight, the electrons reach the conduction band after absorbing the photons of light leaving positive holes in the valence band.
When the electrons are prompted to fall back and recombine with the holes, the electric field in the PN junction separates them and made them travel through the electrical load connected across the panel
then return to recombine with the holes.
The energy of a photon is utilized in exciting electrons which are further used to power the electrical devices.
In this whole process, no extra energy is created but it is only converted into one form to another form.
Hence, validating the law of energy conservation that energy can neither be created nor be destroyed but can only be transformed from one form to another.
So, we conclude that silicon doped with impurities forms the PN junction which further creates a electric field and which in turn helps electrons to flow through the electrical appliances and run them.